Chemistry
28.01.2022 03:05
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Se construye una pila galvánica con una barra de cobre sumergida en una disolución

Se construye una pila galvánica con una barra de cobre sumergida en una disolución 1M de cationes Fe+2 y una barra de plata sumergida en una disolución 1M de da cationes Ag+ , Calcular el potencial estándar de la celda teniendo en cuenta que a 25°C: Cu+2/Cu = -0.34V Ag+/Ag = 0.80V
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hfleysher
hfleysher
5,0(30 marks)

El potencial celular estándar, E_{cell} is +0.46 V

Explanation:

Las reacciones de media célula son;

Media reacción del ánodo Cu²⁺ + 2e⁻ ↔ Cu, E ° = 0.34 V

Media reacción catódica 2Ag + 2e⁻ ⁻ 2Ag, E ° = 0.80 V

Sin embargo tenemos para hierro Fe²⁺ + 2e⁻ ↔ Fe, E ° -0.44 V

y Fe³⁺ + e⁻ ↔ Fe²⁺, E ° = 0.77 V

 que es más alta que la del cobre presente, por lo tanto, el cobre se oxidará en el ánodo

Por lo tanto, en el ánodo, tendremos

Cu → Cu²⁺ + 2e⁻ (E ° = -0.34 V)

En el cátodo

2Ag + 2e⁻ → 2Ag (E ° = 0.80 V)

E_{cell} = E_c + E_a = -0.34 + 0.8 = +0.46 \, V

El potencial celular estándar, E_{cell} = +0.46 V

Fireburntbudder
Fireburntbudder
4,6(48 marks)
They differ in the number of subatomic particles present (electrons, protons and neutrons). They also differ in atomic mass, melting point, boiling point, density and electronegativity.

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