Chemistry
03.03.2022 21:24
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Pure nitrobenzene freezes at 5.67 c. when 1.0g of ethanol (c2h6o) is mixed with

Pure nitrobenzene freezes at 5.67 c. when 1.0g of ethanol (c2h6o) is mixed with 20.0g nitrobenzene, the freeze point drops to โ€“0.53 c. what is the freezing-point depression constant (kf) of nitrobenzene?
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savannahwatson620102
savannahwatson620102
4,9(88 marks)

The freezing-point depression constant (Kf) of nitrobenzene is 5.7^0C/m

Explanation:

Depression in freezing point is given by:

\Delta T_f=i\times K_f\times m

\Delta T_f=T_f^0-T_f=(5.67-(-0.53)^0C=6.2^0C = Depression in freezing point

i= vant hoff factor = 1 (for non electrolyte nitrobenzene)

K_f = freezing point constant = ?

m= molality

\Delta T_f=i\times K_f\times \frac{\text{mass of solute}}{\text{molar mass of solute}\times \text{weight of solvent in kg}}

Weight of solvent = 20 g = 0.02 kg

mass of solute (ethanol) = 1.0 g

Molar mass of ethanol = 46 g/mol

6.2=1\times K_f\times \frac{1.0g}{46g/mol\times 0.02kg}

K_f=5.7^0C/m

Thus freezing-point depression constant (Kf) of nitrobenzene is 5.7^0C/m

djcloverman1905
djcloverman1905
4,8(38 marks)

The question is incomplete, the complete question is:

Standardization of a Borax solution (Na2B4O7). A student titrates a 20.00 mL sample of an aqueous borax solution with 1.044 M H2SO4. It takes 2.63 mL of acid to reach the equivalence point. Knowing it takes 1 H2SO4 to neutralize 2 Na2B4O7, what was the concentration of this Borax solution?

The concentration of borax solution is 0.069 M.

Explanation:

To calculate the concentration of borax solution, the formula used is:

n_1C_1V_1=n_2C_2V_2 ....(1)

where,

n_1, C_1\text{ and }V_1 are the n-factor, concentration and volume of sulfuric acid

n_2,C_2\text{ and }V_2 are the n-factor, concentration and volume of borax solution.

We are given:

n_1=1\\C_1=1.044M\\V_1=2.63mL\\n_2=2\\C_2=?M\\V_2=20mL

Putting values in equation 1, we get:

1\times 1.044\times 2.63=2\times C_2\times 20\\\\C_2=\frac{1\times 1.044\times 2.63}{2\times 20}\\\\C_2=0.069M

Hence, the concentration of borax solution is 0.069 M.

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