Chemistry
13.06.2020 19:24
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g The following equation is given for the dissociation of the complex ion Ag(NH3)

g The following equation is given for the dissociation of the complex ion Ag(NH3) 2. The dissociation constant, Kd, is the equilibrium constant for the dissociation of a complex ion into its component ions. What would be the expression for the dissociation constant of Ag(NH3) 2.
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justhereforanswers13
justhereforanswers13
5,0(38 marks)

Kd = [Ag⁺] × [NH₃]² / [Ag(NH₃)₂⁺]

Explanation:

Let's consider the dissociation reaction of the complex ion Ag(NH₃)₂⁺.

Ag(NH₃)₂⁺(aq) ⇄ Ag⁺(aq) + 2 NH₃(aq)

The dissociation constant, Kd, is the equilibrium constant for the dissociation of the complex ion, that is, it is equal to the product of the concentrations of the products raised to their stoichiometric coefficients divided by the product of the concentrations of the reactants raised to their stoichiometric coefficients.

The dissociation constant for this reaction is:

Kd = [Ag⁺] × [NH₃]² / [Ag(NH₃)₂⁺]

melkumathurin
melkumathurin
4,9(66 marks)

Moles of calcium carbonate : 0.1225

Further explanation

A reaction coefficient is a number in the chemical formula of a substance involved in the reaction equation. The reaction coefficient is useful for equalizing reagents and products.

Reaction

CaCO₃(s) → CaO(s) + CO₂(g)

mass of CaCO₃ : 12.25 g

mol CaCO₃(MW=100 g/mol) :

\tt mol=\dfrac{mass}{MW}\\\\mol=\dfrac{12.25}{100}\\\\mol=0.1225

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