Advanced Placement (AP)
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For the equilibrium: 2 NO​ (g) ​ ⇌ N​ 2(g)​+ O​ 2(g)​at 300 K, the equilibrium constant,

For the equilibrium: 2 NO​ (g) ​ ⇌ N​ 2(g)​+ O​ 2(g)​at 300 K, the equilibrium constant, Kc, is 0.185. If 1.45 moles each of N​ 2(g)​and O​ 2(g)​are introduced in a container that has a volume of 6.00 liters and allowed to reach equilibrium at 300 K, what are the concentrations of N​ 2(g )​ , O​ 2(g)​ ,and NO​ (g)​at equilibrium?
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AM28
AM28
4,9(75 marks)

The concentrations of N_2,O_2\text{ and }NO at equilibrium are 0.112 M, 0.112 M  and 0.260 M

Explanation:

Moles of N_2 = 1.45 mole

Moles of  O_2 = 1.45 mole

Volume of solution = 6.00 L

Initial concentration of N_2 = \frac{moles}{Volume}=\frac{1.45mol}{6.00L}=0.242M

Initial concentration of O_2 = \frac{moles}{Volume}=\frac{1.45mol}{6.00L}=0.242M

The given balanced equilibrium reaction is,

           2NO(g)\rightleftharpoons N_2(g)+O_2(g)

Initial conc.          0 M             0.242 M              0.242 M  

At eqm. conc.     (2x) M      (0.242-x) M        (0.242-x) M

The expression for equilibrium constant for this reaction will be,

K_c=\frac{[N_2]\times [O_2]}{[NO]^2}  

Now put all the given values in this expression, we get :

0.185=\frac{(0.242-x)^2}{(2x)^2}

By solving the term 'x', we get :

x = 0.130

Thus, the concentrations of at equilibrium are :

Concentration of = (0.242-x) M  = (0.242-0.130) M = 0.112 M

Concentration of = (0.242-x) M  = (0.242-0.130) M = 0.112 M

Concentration of = 2x M = = 0.260 M

skylerteaker
skylerteaker
5,0(27 marks)

Put the values in numerical order before trying to find the median. The median is the number in the middle of an ordered set of values. The median must be calculated by finding the mean of the two middle points when there is an even number of

data points.

Explanation:

The median is simply the middle number in an ordered set and is unaffected by outliers. If there are two middle points in an ordered set, then the average of the two numbers is the median.

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